During the formation of a cation, the electrons are lost from the outer shell and the remaining electrons experience a great force of attraction by the nucleolus, ie, attracted more towards the nucleolus. In other words, nucleolus hold the remaining electrons more tightly and this results in decreased radii. However, in case of anion formation, the addition of electron(s) takes place in the same outer shell, thus the hold of nucleolus on the electrons of outer shell decreases and this results in increased ionic radii. Thus, the correct order of ionic radii isS2⋅>Cl−>K+>Ca2+