CBSE Class 12 Chemistry 2022 Term 2 Delhi Set 2
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Question : 3 of 4
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Give reason for the following statements:
(a) Scandium ( is a transition element but is not.
(b) is coloured while is colourless.
(c) Physical and chemical properties of the and series of the transition elements are quite similar than expected.
(a) Scandium ( is a transition element but is not.
(b) is coloured while is colourless.
(c) Physical and chemical properties of the and series of the transition elements are quite similar than expected.
Solution:
(a) On the basis of incompletely filled -orbitals in case of Scandium atom having one electron in its ground state, it is regarded as a transition element. On the other hand, zinc atom having completely filled -orbitals in its ground state as well as in its oxidized state, it is not considered as a transition element.
(b) is coloured because has one unpaired electron which undergoes transition so it is coloured. While has no unpaired electrons so it will not undergo transition so it is colourless.
(c) Physical and chemical properties of and series elements are similar because they have same atomic and ionic radii due to the lanthanide contraction. Due to equal atomic radii the size of and and and , etc., the two elements of each pair have the same properties.
(b) is coloured because has one unpaired electron which undergoes transition so it is coloured. While has no unpaired electrons so it will not undergo transition so it is colourless.
(c) Physical and chemical properties of and series elements are similar because they have same atomic and ionic radii due to the lanthanide contraction. Due to equal atomic radii the size of and and and , etc., the two elements of each pair have the same properties.
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