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Question : 126 of 160
Marks:
+1,
-0
Solution:
If the bond order of species is zero, then species will not exist.
Bond order
H2+−σls1‌‌∴ Bond order
=‌=0.5 He22+−σs2‌‌∴ Bond order
=‌=1 Li22−−σ1s2,σ*1s2,σ2s2,σ*2s2 ∴ Bond order
=‌=0 (do not exist
) ‌Ne2:σls2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2‌‌≈2py2,π*2px2≈π*2py2,σ*2pz2 ∴ Bond order
=‌=0 (do not exist)
Be2−−σ1s2,σ*1s2,σ2s2,σ*2s2,π2px1≈π2py0 ∴ Bond order
=‌=0.5 He2−σls2,σ*ls2 ∴ Bond order
=‌=0( do not exist
) Hence,
Li22−,Ne2 and
He2 will not exist.
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