Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists {en = H_2NCH_2CH_2NH_2; atomic numbers: Ti = 22, Cr = 24; Co = 27; Pt = 78) List - I List - II P. [Cr(NH_3)_3Cl_2]Cl 1. Paramagnetic and exhibits ionization isomerism Q. [Ti(H_2O)_5Cl](NO_3)_2 2. Diamagnetic and exhibits cis-trans isomerism R. [Pt(en)(NH_3)Cl]NO_3 3. Paramagnetic and exhibits cis-trans isomerism S. [Co(NH_3)_4(NO_3)_2]NO_3 4. Diamagnetic and exhibits ionization isomerism [JEE Adv 2014 P2]

Correct Answer is : P - 3, Q - 1, R - 4, S - 2

Coordination Compounds

Section: Chemistry

Question : 28 of 47

Marks: +1, -0

Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists
{en = H‌2NCH‌2CH‌2NH‌2; atomic numbers: Ti = 22, Cr = 24; Co = 27; Pt = 78)

List - I	List - II
P. [Cr(NH‌3)‌3Cl‌2]Cl	1. Paramagnetic and exhibits ionization isomerism
Q. [Ti(H‌2O)‌5Cl](NO‌3)‌2	2. Diamagnetic and exhibits cis-trans isomerism
R. [Pt(en)(NH‌3)Cl]NO‌3	3. Paramagnetic and exhibits cis-trans isomerism
S. [Co(NH‌3)‌4(NO‌3)‌2]NO‌3	4. Diamagnetic and exhibits ionization isomerism

[JEE Adv 2014 P2]

P - 4, Q - 2, R - 3, S - 1
P - 3, Q - 1, R - 4, S - 2
P - 2, Q - 1, R - 3, S - 4
P - 1, Q - 3, R - 4, S - 2

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