Chemical Kinetics and Nuclear Chemistry
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X and Y are two volatile liquids with molar weights of 10 gmol − 1 and 40 g mol − 1 respectively. Two cotton plugs, one soaked in X and the other soaked in Y, are simultaneously placed at the ends of a tube of length L = 24 cm, as shown in the figure. The tube is filled with an inert gas at 1 atmosphere pressure and a temperature of 300 K. Vapours of X and Y react to form a product which is first observed at a distance d cm from the plug soaked in X. Take X and Y to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.
X and Y are two volatile liquids with molar weights of 10 g
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The experimental value of d is found to be smaller than the estimate obtained using Graham’s law. This is due to
[JEE Adv 2014 P2]
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