Thermodynamics

Section: Chemistry
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Question : 21 of 40
 
Marks: +1, -0
The standard state Gibbs free energies of formation of C(graphite) and C(diagram) as T = 298 K are :
ΔfG°[C(graphite)]=0kJmol−1
ΔfG°[C(diamond)]=2.9kJmol−1
The standard state means that the pressure should be 1 bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by 2×10−6m3mol−1
If C(graphite) is converted to C(diamond) isothermally at T = 298 K, the pressure at which C(graphite) is in equilibrium with C(diamond), is: [Useful information: 1J=1kgm2s−2; 1Pa=1kgm−1s−2; 1bar=105Pa]
[JEE Adv 2017 P2]
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