AIPMT 2010 Physics and Chemistry Paper

Reducing sugars that exist in hemiacetal and hemiketal forms, undergo mutarotation in aqueous solution. Among the given carbohydrates, only sucrose is a non-reducing sugar as in it the hemiacetal and hemiketal groups of glucose and fructose are linked together through O-atom and thus, not free. Due to the absence of free hemiacetal or hemiketal group, sucrose does not exhibit mutarotation.