AIEEE 2010 Solved Paper
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Question : 20 of 89
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Consider the reaction :
Cl 2 ( aq ) + H 2 S ( aq ) → S ( s ) + 2 H + ( aq ) + 2 Cl − ( aq )
The rate equation for this reaction is rate = k [ Cl 2 ] [ H 2 S ]
Which of these mechanisms is/are consistent with this rate equation?
(A)Cl 2 + H 2 S → H + + Cl − + Cl + + HS − (slow)
Cl + + HS − → H + + Cl − + S (fast)
(B)H 2 S ⇔ H + + HS − (fast equilibrium)
Cl 2 + HS − → 2 Cl − + H + + S (slow)
Which of these mechanisms is/are consistent with this rate equation?
(A)
(B)
[AIEEE 2010]
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