CBSE Class 12 Chemistry 2023 Delhi Set 2 Solved Paper
© examsiri.com
Question : 12 of 12
Marks:
+1,
-0
SECTION - D
(a) A transition element has electronic configuration , Predict its likely oxidation states. (b) Complete the reaction mentioning all the products formed:
(c) Account for the following
(i) In the 3d transition series, zinc has the lowest, enthalpy of atomisation.
(ii) ion is unstable in aqueous solution.
(iii) Actinoids show more number of oxidation states than lanthanoids.
Solution:
(a) The -element is vanadium (V)
Its electronic configuration is [Ar]
Likely oxidation state:
(b)
(c) (i)
The d-orbital is fully filled in zinc (Zn). There is no unpaired electrons are available. Inter atomic bonding is weak because of which metallic bonding is also weak.
(ii)
In aqueous medium it exist as loosing one but because of high hydration enthalpy it readily converted into . It also show disproportion reaction because of which the reaction take place.
(iii) Actinoids are radioactive in nature. They have almost similar enthalpy of actinides. Therefore, they shows more actinoids contraction than lanthinoids contraction. They have more poor shielding of orbitals than orbitals.
Its electronic configuration is [Ar]
Likely oxidation state:
(b)
(c) (i)
The d-orbital is fully filled in zinc (Zn). There is no unpaired electrons are available. Inter atomic bonding is weak because of which metallic bonding is also weak.
(ii)
In aqueous medium it exist as loosing one but because of high hydration enthalpy it readily converted into . It also show disproportion reaction because of which the reaction take place.
(iii) Actinoids are radioactive in nature. They have almost similar enthalpy of actinides. Therefore, they shows more actinoids contraction than lanthinoids contraction. They have more poor shielding of orbitals than orbitals.
© examsiri.com
Go to Question: