CBSE Class 12 Chemistry 2019 Outside Delhi Set 2 Solved Paper
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Question : 14 of 27
Marks:
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The following data were obtained for the reaction:
(a) Find the order of reaction with respect to and .
(b) Write the rate law and overall order of reaction.
(c) Calculate the rate constant (k).
| Experiment | |||
|---|---|---|---|
| 1 | 0.2 | 0.3 | |
| 2 | 0.1 | 0.1 | |
| 3 | 0.4 | 0.3 | |
| 4 | 0.1 | 0.4 |
(a) Find the order of reaction with respect to and .
(b) Write the rate law and overall order of reaction.
(c) Calculate the rate constant (k).
Solution:
Let the order of reaction with respect to be and with respect to B be .
According to details given ,
.....(1)
.......(2)
.......(3)
........(4)
Dividing equation (4) by (2), we get
Dividing equation (1) by (3), we get
(a) So the rate of reaction with respect to is 2 and with respect to is 1 .
(b) Rate law Overall order of reaction is 3 .
(c) Rate constant,
According to details given ,
.....(1)
.......(2)
.......(3)
........(4)
Dividing equation (4) by (2), we get
Dividing equation (1) by (3), we get
(a) So the rate of reaction with respect to is 2 and with respect to is 1 .
(b) Rate law Overall order of reaction is 3 .
(c) Rate constant,
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